Methanol In Homemade Alcohol (Wood Alcohol) while brewing

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Methanol In Homemade Alcohol (Wood Alcohol) while brewing

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What is Methanol

Methanol in homemade alcohol is a colourless, flammable liquid with a very distinct smell and taste when pure. However, it is difficult to smell or taste when mixed with a soft drink like coke.

The danger here is that when concentrated to high levels, it can be fatal if consumed in large quantities, which ends up being methanol poisoning.  

The body converts methanol to formaldehyde and formic acid, which can cause blindness and possibly lead to death.  

Where can I find methanol?

Methanol, also known as methyl alcohol or wood alcohol, is a toxic alcohol that can be present in some alcoholic beverages: 

Home-distilled spirits: Methanol in homemade alcohol can accumulate in home-distilled spirits like gin or rum because the distillation process doesn’t always separate methanol from ethanol. (mash and NOT SUGAR WASH)

All spirits have some amount of methanol in them. Note the brewer makes sure it is safe to drink due to regulations! Have you ever noticed a hangover the next day, more of a hangover means more methanol in your alcohol ie the alcohol was bad quality for example Absolut Vodka vs cheaply made vodka.

Other sources of methanol include:

Windshield washer fluid

Gas line antifreeze

Carburettor cleaner

Perfumes

The Formulae of Methanol and Ethanol


Methanol Formulae – CH3OH

Boiling point (BP) = 64.7°C (148.4°F)

Mole weight = 32.04 g/mol


Ethanol Formulae  – CH3CH2OH

Boiling point (BP) = 78°C (172.4°F)

Mole weight = 46.07 g/mol

As can be seen, there is a distinct difference in the mole weight and boiling point of ethanol versus methanol. So for you to get methanol into the ethanol should never happen!

How Is Methanol Removed From the Fermented Solution

Distillation is used to separate the CH3 (primary alcohol) methanol in homemade alcohol from the mixture.

Note: Methanol BP is 64.7°C (148.4°F) and Ethanol BP is 78°C (172.4°F), the mole weights differ by up to 30 points. This will be removed as foreshots and heads with other undesirables when making cuts.

How Can We Get Methanol Into Spirits That We Drink?

Methanol must be removed during distillation of the spirits. For you to get methanol into spirits, the distiller has not separated the foreshots and heads from the hearts… That means bad quality and a bad distiller. 

How Dangerous Is This?

There is no real problem when making beer as the methanol percentage concentration is low. 

Methanol from a mash ferment that is re-distilled several times (concentrated) is where the problem can happen. 

Methanol is formed during mash fermentation for example when whisky is made using a recipe that uses pectin, fruits, barley, and corn products. 

This mash is distilled in a pot still that allows the hot vapour to pass through the swan neck to the condenser. Responsible brewers can easily remove this from the mix as a cut.

Consumption of 10ml of concentrated pure methanol is lethal. What this means is that moonshine containing 10ml of methanol is fatal which is methanol poisoning. (rot-gut of old) 

Bad brewers can make batches of ferment high in methanol. When distilled, it is possible to concentrate the ferment and boil it over to the hearts. 

How Can Methanol Be Tested?

Instruments in a lab 

DIY take a sample and burn it. The Ethanol tip should burn blue or clear, if the tip burns black/white, drink at your peril.

Good to know – how can you sense methanol in your drink

Unfortunately, once you mix the drink it is almost impossible to tell (smell and taste) if it is contaminated. Methanol mixes with water like ethanol plus the methanol is colourless.

Should you get sick or have one hell of a hangover then you have drunk spirits that have not been correctly separated in the distillation phase. Buying from stalls and any dodgy bars. 

From these stalls, you must smell the spirits before they dilute with a soda/cool drink. Should it not smell right (medical smell) or taste, colour is wrong don’t drink it.


Last Updated on Jan 09, 2025 by The Brew Mechanic

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With 35 years of knowledge of being a chemical engineer in alcohol manufacturing plants, my mission is to teach the next generation of home distilling alcohol brewers at a supernatural speed.

My reviews are based on real-life experiences with reflux stills, sugar wash, troubleshooting and mystical chemical reactions.

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